An acidic layered clay is combined with a basic layered clay for one-pot sequential reactions

被引：166

作者：

Motokura, K ^{[1
]}

Fujita, N ^{[1
]}

Mori, K ^{[1
]}

Mizugaki, T ^{[1
]}

Ebitani, K ^{[1
]}

Kaneda, K ^{[1
]}

机构：

[1] Osaka Univ, Grad Sch Engn, Dept Mat Engn Sci, Toyonaka, Osaka 5608531, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 27期

关键词：

D O I：

10.1021/ja052386p

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A Ti4+-exchanged montmorillonite (Ti4+-mont) and a hydrotalcite (HT) are strong solid Brønsted acid and base, and these two clay catalysts could be used in a single reactor without neutralization of active sites. Because the Ti4+-mont have active acid site in the narrow interlayers, the base sites of large HT particles show no interaction with the acid sites. A variety of acid and base reactions, such as esterification, acetalization, deacetalization, aldol reaction, Michael reaction, and epoxidation, proceeded using both the Ti4+-mont and the HT in a single reactor. Copyright © 2005 American Chemical Society.

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页码：9674 / 9675

页数：2

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