Tris(tert-butylcyclopentadienyl)praseodymium-μ-bromo-tris(tetrahydrofuran)-lithium

被引：4

作者：

Luo, YJ ^{[1
]}

Yao, YM

Shen, Q

Sun, J

Xue, F

机构：

[1] Suzhou Univ, Dept Chem, Suzhou 215006, Peoples R China

[2] Chinese Acad Sci, Shanghai Inst Organ Chem, Shanghai 200032, Peoples R China

[3] Chinese Univ Hong Kong, Dept Chem, Hong Kong, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1998年 / 54卷

关键词：

D O I：

10.1107/S0108270197015199

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title complex [{Li(C4H8O)(3)}Br{Pr(C9H13)(3)}] has a distorted pseudo-tetrahedral geometry around the ten-coordinate Pr atom. The ((BuCp)-Bu-t)(3)Pr unit and Li(thf)(3)(+) cation (where thf is tetrahydrofuran) are connected by a mu-Br atom. The Pr-Br and Li-Br distances are 2.995(1) and 2.495(15) Angstrom, respectively, and the Pr-Br-Li angle is 137.3(3)degrees.

引用

页码：711 / 712

页数：2

共 12 条

[1]

GAO HR, 1992, J ORGANOMET CHEM, V427, P141

[2] TRIS(TERT-BUTYLCYCLOPENTADIENYL)NEODYMIUM-MU-CHLORO-TRIS(TETRAHYDROFURAN)LITHIUM, [ND(ETA(5)-(T)BUCP)3(MU-CL)LI(THF)3] [J].