Monomeric (dialkylamino)boranes: a new and efficient boron source in palladium catalyzed C-B bond formation with aryl halides

被引:79
作者
Euzenat, L [1 ]
Horhant, D [1 ]
Ribourdouille, Y [1 ]
Duriez, C [1 ]
Alcaraz, G [1 ]
Vaultier, M [1 ]
机构
[1] Univ Rennes 1, CNRS, UMR 6510, SESO, F-35042 Rennes, France
关键词
D O I
10.1039/b306874a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Thermal decomposition of hindered amine-borane adducts leads in high yields to monomeric (dialkylamino)boranes R1R2N-BH2 (R-1 and R-2 = alkyl) that are new and efficient boron-sources in the Pd-0 catalyzed borylation reaction affording monomeric aryl(dialkylamino)boranes R1R2N-BHR3 (R-3 = aryl).
引用
收藏
页码:2280 / 2281
页数:2
相关论文
共 29 条
  • [11] Stoichiometric and catalytic B-C bond formation from unactivated hydrocarbons and boranes
    Iverson, CN
    Smith, MR
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (33) : 7696 - 7697
  • [12] Rhodium-catalyzed formation of boron-nitrogen bonds: a mild route to cyclic aminoboranes and borazines
    Jaska, CA
    Temple, K
    Lough, AJ
    Manners, I
    [J]. CHEMICAL COMMUNICATIONS, 2001, (11) : 962 - 963
  • [13] Rhodium-catalyzed, regiospecific functionalization of polyolefins in the melt
    Kondo, Y
    García-Cuadrado, D
    Hartwig, JF
    Boaen, NK
    Wagner, NL
    Hillmyer, MA
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (07) : 1164 - 1165
  • [14] KOSTER R, 1969, LIEBIGS ANN CHEM, V720, P32
  • [15] Maringgele W, 1999, MAIN GROUP MET CHEM, V22, P715
  • [16] Maringgele W, 2000, MAIN GROUP MET CHEM, V23, P735
  • [17] Miyashita N., 2001, Chemical-Mechanical Polishing 2000 - Fundamentals and Materials Issues. Symposium (Materials Research Society Symposium Proceedings Vol.613), P1, DOI 10.1002/3527600159.ch1
  • [18] MIYAURA N, 1998, ADV METAL ORGANIC CH, V6, P210
  • [19] Palladium-catalyzed borylation of aryl halides or triflates with dialkoxyborane: A novel and facile synthetic route to arylboronates
    Murata, M
    Oyama, T
    Watanabe, S
    Masuda, Y
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2000, 65 (01) : 164 - 168
  • [20] Novel palladium(0)-catalyzed coupling reaction of dialkoxyborane with aryl halides: Convenient synthetic route to arylboronates
    Murata, M
    Watanabe, S
    Masuda, Y
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 1997, 62 (19) : 6458 - 6459