Silver-mediated synthesis of heterocycles

被引：532

作者：

Alvarez-Corral, Miriam ^{[1
]}

Munoz-Dorado, Manuel ^{[1
]}

Rodirguez-Garcia, Ignacio ^{[1
]}

机构：

[1] Univ Almeria, Dpt Quim Organ, Almeria 04120, Spain

来源：

CHEMICAL REVIEWS | 2008年 / 108卷 / 08期

关键词：

D O I：

10.1021/cr078361l

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A summary on heterocyclizations wherein silver salts are an important aspect of it has been given. These include: the addition of nucleophiles to alkynes, allenes, and olefins; the cycloaddition reactions that focuses on enantioselective [3+2]-cycloaddition of azomethine ylides and nitrilimines and [4+2]-cycloaddition of imines. It has been found out that silver complexes are efficiently catalyzing the intramolecular addition of oxygen and nitrogen nucleophiles to alkynes, allenes and olefins. A useful route can be provided by this silver-catalyzed asymmetric aza-Diels-Alder reactions to optically active nitrogen-heterocyclic compounds. Furthermore, silver is capable of enriching heterocyclization methods and is useful for chiral silver complexes.

引用

页码：3174 / 3198

页数：25

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