Nickel-catalyzed regio- and stereo-selective synthesis of homoallylic alcohol derivatives from dienes and aldehydes

被引：82

作者：

Takimoto, M ^{[1
]}

Hiraga, Y ^{[1
]}

Sato, Y ^{[1
]}

Mori, M ^{[1
]}

机构：

[1] Hokkaido Univ, Grad Sch Pharmaceut Sci, Sapporo, Hokkaido 0600812, Japan

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 25期

基金：

日本学术振兴会;

关键词：

aldehydes; coupling reactions; dienes; hydrosilane; nickel;

D O I：

10.1016/S0040-4039(98)00827-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reaction of 1,3-Dienes and aldehydes in the presence of Et3SiH using a catalytic amount of Ni(cod)(2) and PPh3 gave homoallylic alcohol derivatives in a regio-and stereoselective manner. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：4543 / 4546

页数：4

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