Highly stereoselective reduction of 4-Aryl-2-oxo but-3-enoic carboxylic esters by plant cell culture of Daucus carota

被引：40

作者：

Baskar, B

Ganesh, S

Lokeswari, TS

Chadha, A ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, Madras 600036, Tamil Nadu, India

[2] SPIC Sci Fdn, Div Biotechnol, Madras 600032, Tamil Nadu, India

来源：

JOURNAL OF MOLECULAR CATALYSIS B-ENZYMATIC | 2004年 / 27卷 / 01期

关键词：

Daucus carota; plant tissue culture; asymmetric reduction; alpha-hydroxy beta; gamma-unsaturated arylidine esters;

D O I：

10.1016/j.molcatb.2003.09.004

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

A highly enantioselective preparation (92-99% enantiomeric excess, 100% conversion) of various 4-aryl-2-hydroxy but-3-enoic carboxylic acid esters from the corresponding 4-phenyl-2-keto but-3-enoic acid esters mediated by plant cell cultures of Daucus carota under mild and environmentally benign conditions in aqueous medium is described. (C) 2003 Elsevier B.V All rights reserved.

引用

页码：13 / 17

页数：5

共 35 条

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