High resolution electronic spectroscopy and an empirical potential energy surface for Ne.SH/D

被引:18
作者
Carter, CC [1 ]
Miller, TA [1 ]
Lee, HS [1 ]
McCoy, AB [1 ]
Hayes, EF [1 ]
机构
[1] Ohio State Univ, Dept Chem, Laser Spect Facil, Columbus, OH 43210 USA
关键词
D O I
10.1063/1.478395
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The high resolution, laser-induced fluorescence (A) over tilde (2)Sigma(+) <-> (X) over tilde (2)Pi spectra of the Ne . SH van der Waals complex and its deuterated analog are reported. The rotational analyses provide information about the fine, hyperfine, spin-rotation, and parity interactions in these two complexes. These results are used in conjunction with measured vibrational intervals to develop an empirical potential energy surface for Ne . SH/D. (C) 1999 American Institute of Physics. [S0021-9606(99)01811-5].
引用
收藏
页码:5065 / 5078
页数:14
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