An Isoreticular Series of Metal-Organic Frameworks with Dendritic Hexacarboxylate Ligands and Exceptionally High Gas-Uptake Capacity

被引：686

作者：

Yuan, Daqiang ^{[1
]}

Zhao, Dan ^{[1
]}

Sun, Daofeng ^{[2
]}

Zhou, Hong-Cai ^{[1
]}

机构：

[1] Texas A&M Univ, Dept Chem, College Stn, TX 77843 USA

[2] Shandong Univ, Key Lab Colloid & Interface Chem, Jinan 250100, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 31期

基金：

美国国家科学基金会;

关键词：

carbon storage; clean energy; hydrogen; metal-organic frameworks; methane; HYDROGEN UPTAKE; SURFACE-AREA; STORAGE; ADSORPTION; POROSITY; DESIGN; CARBON; ROUTE;

D O I：

10.1002/anie.201001009

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Holding gas: One of the isoreticular metal-organic frameworks (MOFs) that have been synthesized and characterized structurally, PCN-68 (see structure), has a Langmuir surface area of as high as 6033 m 2 g-1. The MOFs also display excellent gas (H2, CH4, and CO2) adsorption capacity. © 2010 Wiley-vCH Verlag GmbH & Co. KGaA.

引用

页码：5357 / 5361

页数：5

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