An Isoreticular Series of Metal-Organic Frameworks with Dendritic Hexacarboxylate Ligands and Exceptionally High Gas-Uptake Capacity

被引：686

作者：

Yuan, Daqiang ^{[1
]}

Zhao, Dan ^{[1
]}

Sun, Daofeng ^{[2
]}

Zhou, Hong-Cai ^{[1
]}

机构：

[1] Texas A&M Univ, Dept Chem, College Stn, TX 77843 USA

[2] Shandong Univ, Key Lab Colloid & Interface Chem, Jinan 250100, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 31期

基金：

美国国家科学基金会;

关键词：

carbon storage; clean energy; hydrogen; metal-organic frameworks; methane; HYDROGEN UPTAKE; SURFACE-AREA; STORAGE; ADSORPTION; POROSITY; DESIGN; CARBON; ROUTE;

D O I：

10.1002/anie.201001009

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Holding gas: One of the isoreticular metal-organic frameworks (MOFs) that have been synthesized and characterized structurally, PCN-68 (see structure), has a Langmuir surface area of as high as 6033 m 2 g-1. The MOFs also display excellent gas (H2, CH4, and CO2) adsorption capacity. © 2010 Wiley-vCH Verlag GmbH & Co. KGaA.

引用

页码：5357 / 5361

页数：5

共 28 条

[11] Carbon Capture and Storage: How Green Can Black Be? [J].

Haszeldine, R. Stuart .

SCIENCE, 2009, 325 (5948) :1647-1652

[12] Functional porous coordination polymers [J].

Kitagawa, S ;

Kitaura, R ;

Noro, S .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (18) :2334-2375

[13]

Klein N., 2009, ANGEW CHEM, V121, P10139

[14] A Mesoporous Metal-Organic Framework [J].

Klein, Nicole ;

Senkovska, Irena ;

Gedrich, Kristina ;

Stoeck, Ulrich ;

Henschel, Antje ;

Mueller, Uwe ;

Kaskel, Stefan .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (52) :9954-9957

[15] A Porous Coordination Copolymer with over 5000 m2/g BET Surface Area [J].

Koh, Kyoungmoo ;

Wong-Foy, Antek G. ;

Matzger, Adam J. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (12) :4184-+

[16] Highly Porous and Robust 4,8-Connected Metal-Organic Frameworks for Hydrogen Storage [J].

Ma, Liqing ;

Mihalcik, David J. ;

Lin, Wenbin .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (13) :4610-+

[17] Framework-catenation isomerism in metal-organic frameworks and its impact on hydrogen uptake [J].

Ma, Shengqian ;

Sun, Daofeng ;

Ambrogio, Michael ;

Fillinger, Jacqueline A. ;

Parkin, Sean ;

Zhou, Hong-Cai .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (07) :1858-+

[18] Gas storage in porous metal-organic frameworks for clean energy applications [J].

Ma, Shengqian ;

Zhou, Hong-Cai .

CHEMICAL COMMUNICATIONS, 2010, 46 (01) :44-53

[19] Metal-organic frameworks -: prospective industrial applications [J].

Mueller, U ;

Schubert, M ;

Teich, F ;

Puetter, H ;

Schierle-Arndt, K ;

Pastré, J .

JOURNAL OF MATERIALS CHEMISTRY, 2006, 16 (07) :626-636

[20] Hydrogen storage in metal-organic frameworks [J].

Murray, Leslie J. ;

Dinca, Mircea ;

Long, Jeffrey R. .

CHEMICAL SOCIETY REVIEWS, 2009, 38 (05) :1294-1314

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