Preparation and structures of homoleptic Pu(III) and U(III) acetonitrile salts

被引：28

作者：

Enriquez, AE ^{[1
]}

Matonic, JH ^{[1
]}

Scott, BL ^{[1
]}

Neu, MP ^{[1
]}

机构：

[1] Los Alamos Natl Lab, Div Chem, C SIC, Los Alamos, NM 87545 USA

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 15期

关键词：

D O I：

10.1039/b303558a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Nine-coordinate homoleptic acetonitrile solvate complexes of Pu(III) and U(III) ions have been prepared through oxidation of Pu metal suspended in acetonitrile with metal-hexafluorophosphate salts and dissolution of UI3(THF)(4) in acetonitrile, respectively.

引用

页码：1892 / 1893

页数：2

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