Real-Time Observation of the Self-Assembly of Hybrid Polyoxometalates Using Mass Spectrometry

被引：129

作者：

Wilson, Elizabeth F. ^{[1
]}

Miras, Haralampos N. ^{[1
]}

Rosnes, Mali H. ^{[1
]}

Cronin, Leroy ^{[1
]}

机构：

[1] Univ Glasgow, Dept Chem, WestCHEM, Glasgow G12 8QQ, Lanark, Scotland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 16期

基金：

英国工程与自然科学研究理事会;

关键词：

manganese; mass spectrometry; polyoxometalates; self-assembly; BUILDING-BLOCKS; SOLID-STATE; ELECTROSPRAY; CLUSTERS; POLYMERS; POLYOXOMOLYBDATE; IDENTIFICATION; COMPLEXITIES; DERIVATIVES; CHEMISTRY;

D O I：

10.1002/anie.201006938

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Graph Presented) Catching a glimpse: Electrospray ionization mass spectrometry (ESI-MS) allows monitoring of the real-time, "in- solution" formation of an organic-inorganic poly-oxometalate hybrid system (see picture). This has provided insight into the rearrangement involved in the formation of the manganese-Anderson cluster coordinated with tris(hydroxymethyl)aminomethane ligands, through the rearrangement of the [α-Mo8O26]4- cluster in the presence of Mn(CH3CO2)3. © 2011 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：3720 / 3724

页数：5

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