Real-Time Observation of the Self-Assembly of Hybrid Polyoxometalates Using Mass Spectrometry

被引：129

作者：

Wilson, Elizabeth F. ^{[1
]}

Miras, Haralampos N. ^{[1
]}

Rosnes, Mali H. ^{[1
]}

Cronin, Leroy ^{[1
]}

机构：

[1] Univ Glasgow, Dept Chem, WestCHEM, Glasgow G12 8QQ, Lanark, Scotland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 16期

基金：

英国工程与自然科学研究理事会;

关键词：

manganese; mass spectrometry; polyoxometalates; self-assembly; BUILDING-BLOCKS; SOLID-STATE; ELECTROSPRAY; CLUSTERS; POLYMERS; POLYOXOMOLYBDATE; IDENTIFICATION; COMPLEXITIES; DERIVATIVES; CHEMISTRY;

D O I：

10.1002/anie.201006938

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Graph Presented) Catching a glimpse: Electrospray ionization mass spectrometry (ESI-MS) allows monitoring of the real-time, "in- solution" formation of an organic-inorganic poly-oxometalate hybrid system (see picture). This has provided insight into the rearrangement involved in the formation of the manganese-Anderson cluster coordinated with tris(hydroxymethyl)aminomethane ligands, through the rearrangement of the [α-Mo8O26]4- cluster in the presence of Mn(CH3CO2)3. © 2011 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：3720 / 3724

页数：5

共 51 条

[11] HYDROLYTICALLY STABLE ORGANIC TRIESTER CAPPED POLYOXOMETALATES WITH CATALYTIC OXYGENATION ACTIVITY OF FORMULA [RC(CH2O)3V3P2W15O59]6- (R=CH3, NO2, CH2OH) [J].

HOU, YQ ;

HILL, CL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (25) :11823-11830

[12] A survey of applications of polyoxometalates [J].

Katsoulis, DE .

CHEMICAL REVIEWS, 1998, 98 (01) :359-387

[13] A HIGH-NUCLEARITY POLYOXOALKOXOMOLYBDATE CLUSTER ENCAPSULATING A [NA(H2O)3]+ MOIETY - HYDROTHERMAL SYNTHESIS AND STRUCTURE OF [NA(H2O)3H15MO42O109((OCH2)3CCH2OH)7]7- [J].

KHAN, MI ;

ZUBIETA, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (25) :10058-10059

[14] HEXAVANADIUM POLYOXO ALKOXIDE ANION CLUSTERS - STRUCTURES OF THE MIXED-VALENCE SPECIES (ME3NH)[V(IV)5V(V)O7(OH)3(CH3C(CH2O)3)3] AND OF THE REDUCED COMPLEX NA2[V(IV)6O7(CH3CH2C(CH2O)3)4] [J].

KHAN, MI ;

CHEN, Q ;

ZUBIETA, J ;

GOSHORN, DP .

INORGANIC CHEMISTRY, 1992, 31 (09) :1556-1558

[15] Catalysis by heteropoly acids and multicomponent polyoxometalates in liquid-phase reactions [J].

Kozhevnikov, IV .

CHEMICAL REVIEWS, 1998, 98 (01) :171-198

[16] MOLYBDENUM(VI) COMPLEXES OF BRANCHED LIGANDS WITH [N,O,O,O] AND [O,O,O] DONOR SETS - THE CRYSTAL AND MOLECULAR-STRUCTURES OF [MOO2(HOC2H4N(C2H4O)2)], [(N-C4H9)4N]2[MO2O4(O2NC(CH2O)3)2].2O2NC(CH2OH)3, [(N-C4H9)4N]2[MO2O5(HO2CCH2N(CH2CO2)2)2].H2O AND [(N-C4H9)4N][MO3O6(OCH3)(CH3C(CH2O)3)2] [J].

LIU, SC ;

MA, LD ;

MCGOWTY, D ;

ZUBIETA, J .

POLYHEDRON, 1990, 9 (13) :1541-1553

[17] Unravelling the complexities of polyoxometalates in solution using mass spectrometry: Protonation versus heteroatom inclusion [J].

Long, De-Liang ;

Streb, Carsten ;

Song, Yu-Fei ;

Mitchell, Scott ;

Cronin, Leroy .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (06) :1830-+

[18] Polyoxometalate clusters, nanostructures and materials: From self assembly to designer materials and devices [J].

Long, De-Liang ;

Burkholder, Eric ;

Cronin, Leroy .

CHEMICAL SOCIETY REVIEWS, 2007, 36 (01) :105-121

[19] Polyoxometalates: Building Blocks for Functional Nanoscale Systems [J].

Long, De-Liang ;

Tsunashima, Ryo ;

Cronin, Leroy .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (10) :1736-1758

[20] SYNTHESIS AND CHARACTERIZATION OF A TRINUCLEAR POLYOXOMOLYBDATE CONTAINING A REACTIVE [M0O3] UNIT, [(N-C4H9)4N]2[MO3O7(CH3C(CH2O)3)2], AND ITS CONVERSION TO THE METHOXY DERIVATIVE [(N-C4H9)4N][MO3O6(OCH3)(CH3C(CH2O)3)2] [J].

MA, L ;

LIU, SC ;

ZUBIETA, J .

INORGANIC CHEMISTRY, 1989, 28 (02) :175-177

← 1 2 3 4 5 6 →