Adsorption of Cr(VI) onto PEI immobilized acrylate-based magnetic beads: Isotherms, kinetics and thermodynamics study

被引：214

作者：

Bayramoglu, Guelay ^{[1
]}

Arica, M. Yakup ^{[1
]}

机构：

[1] Kirikkale Univ, Fac Sci, Biochem Proc & Biomat Res Lab, TR-71450 Yahsihan, Kirikkale, Turkey

来源：

CHEMICAL ENGINEERING JOURNAL | 2008年 / 139卷 / 01期

关键词：

magnetic beads; PEI; adsorption; heavy metal; Cr(VI); adsorption modelling; kinetic characterization;

D O I：

10.1016/j.cej.2007.07.068

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

Magnetic poly(GMA-EGDMA) beads were prepared from glycidylmetharylate (GMA) and ethyleneglycol dimethacrylate (EGDMA) in the presence of Fe3O4 nano-powder via suspension polymerization. After polymerization, the magnetic beads were coated with polyethyleneinnine (PEI). Elemental analysis of PEI immobilized beads for the free amine group content was estimated as 258.8 mu mol/g polymer. The magnetic beads were characterized by surface area measurement, electron spin resonance (ESR), and scanning electron microscopy (SEM). ESR data revealed that the beads were highly super-paramagnetic. The magnetic beads were used for the removal of Cr(VI) ions from aqueous solutions in batch mode. Adsorption equilibrium was established in about 120 min. The maximum adsorption of Cr(VI) on the magnetic beads was observed at around pH 2.0. The maximum adsorption capacity of the magnetic beads was 137.7 mg/g. The effects of adsorbent dosage, ionic strength and temperature have been also reported. (C) 2007 Elsevier B.V. All rights reserved.

引用

页码：20 / 28

页数：9

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