Adipic acid assisted sol-gel synthesis of Li2MnSiO4 nanoparticles with improved lithium storage properties

被引：96

作者：

Aravindan, V. ^{[1
]}

Karthikeyan, K. ^{[1
]}

Ravi, S. ^{[2
]}

Amaresh, S. ^{[1
]}

Kim, W. S. ^{[3
]}

Lee, Y. S. ^{[1
]}

机构：

[1] Chonnam Natl Univ, Fac Appl Chem Engn, Kwangju 500757, South Korea

[2] Mepco Schlenk Engn Coll, Dept Phys, Sivakasi 626005, India

[3] Dajung EM Co Ltd, Inchon 405820, South Korea

来源：

JOURNAL OF MATERIALS CHEMISTRY | 2010年 / 20卷 / 35期

关键词：

ELECTROCHEMICAL PERFORMANCE; CATHODE MATERIAL; LI2FESIO4; LIFEPO4;

D O I：

10.1039/c0jm01635g

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

An adipic acid assisted sol-gel route was employed to prepare phase pure Li2MnSiO4 under the optimized conditions. Powder X-ray diffraction measurements confirm the formation of orthorhombic Li2MnSiO4 with Pmn2(1) space group. The oxidation state of Mn(II) was confirmed by electron paramagnetic resonance (EPR) studies. FTIR study was conducted to ensure the formation of a tetrahedral SiO4 group. Morphological features confirmed the appearance of evenly dispersed Li2MnSiO4 spherical nanoparticles with size of similar to 30 nm. The Li/Li2MnSiO4 cell was constructed to study the electrochemical performance of Li2MnSiO4 nanoparticles and the cell delivers a stable discharge capacity profile (similar to 125 mAh g(-1)) for observed 50 cycles.

引用

页码：7340 / 7343

页数：4

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