High capacitive performance of nanostructured Mn-Ni-Co oxide composites for supercapacitor

被引:102
作者
Luo, Jian-Min [2 ]
Gao, Bo [1 ]
Zhang, Xiao-Gang [1 ]
机构
[1] Nanjing Univ Aeronaut & Astronaut, Coll Mat Sci & Engn, Nanjing 210016, Peoples R China
[2] Xinjiang Univ, Inst Appl Chem, Urumqi 830046, Peoples R China
基金
中国国家自然科学基金;
关键词
nanostructures; oxides; chemical synthesis; electrochemical measurement; electrochemical properties;
D O I
10.1016/j.materresbull.2007.06.006
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Nanostructured Mn-Ni-Co oxide composites (MNCO) were prepared by thermal decomposition of the precursor obtained by chemical co-precipitation of Mn, Ni and Co salts. The chemical composition and morphology were characterized by X-ray diffraction (XRD), energy dispersive spectroscopy (EDS) and scanning electron microscopy (SEM). The electrochemical capacitance of MNCO electrode was examined by cyclic voltammetry, impedance and galvanostatic charge-discharge measurements. The results showed that MNCO electrode exhibited the good electrochernical characteristics. A maximum capacitance value of 1260 F g(-1) could be obtained within the potential range of -0.1 to 0.4 V versus saturated calomel electrode (SCE) in 6 mol L-1 KOH electrolyte. (C) 2007 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1119 / 1125
页数:7
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