Ascertaining the 1D hydrogen-bonded network in organic ionic solids

被引：69

作者：

Ballabh, A ^{[1
]}

Trivedi, DR ^{[1
]}

Dastidar, P ^{[1
]}

机构：

[1] Cent Salt & Marine Chem Res Inst, Analyt Sci Discipline, Bhavnagar 364002, Gujarat, India

来源：

CRYSTAL GROWTH & DESIGN | 2005年 / 5卷 / 04期

关键词：

D O I：

10.1021/cg050020i

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Crystal engineering concepts are exploited to generate a 1D hydrogen-bonded network in a series of organic salts (9-18) derived from dicyclohexylamine and various dicarboxylic acids (1-7) having linear as well as twisted/angular functional topology. It is clearly demonstrated that the cyclic OD hydrogen-bonded network involving corresponding cations and anions in a secondary ammonium monocarboxylate salt (synthon B or C) can indeed be transformed into a 1D network in 1:2 (acid/amine) dicarboxylate systems (9-12). The effects of the twisted/angular functional topology of the anion moiety on the resultant supramolecular architectures in the corresponding 1:2 (acid/amine) salts (13-15) are examined. The 1:1 salts (16-18) of the dicarboxylic acids having twisted/angular functional topology also display a 1D network.

引用

页码：1545 / 1553

页数：9

共 45 条

[11] HYDROGEN-BOND-DIRECTED SELF-ASSEMBLY OF D-(+)-DIBENZOYL TARTARIC ACID AND 4-AMINOPYRIDINE - OPTICAL NONLINEARITIES AND STOICHIOMETRY-DEPENDENT NOVEL STRUCTURAL FEATURES [J].

BHATTACHARYA, S ;

DASTIDAR, P ;

ROW, TNG .

CHEMISTRY OF MATERIALS, 1994, 6 (04) :531-537

[12] BINARY SALTS OF SUBSTITUTED PYRIDINES AND L-TARTARIC ACID AS NONLINEAR-OPTICAL ORGANIC MATERIALS - CRYSTAL-STRUCTURE OF L-TARTARIC ACID-4-DIMETHYLAMINOPYRIDINE (1/1) DIHYDRATE SALT [J].

DASTIDAR, P ;

ROW, TNG ;

PRASAD, BR ;

SUBRAMANIAN, CK ;

BHATTACHARYA, S .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1993, (12) :2419-2422

[13]

Desiraju G. R., 1989, DESIGN ORGANIC SOLID

[14] SUPRAMOLECULAR SYNTHONS IN CRYSTAL ENGINEERING - A NEW ORGANIC-SYNTHESIS [J].

DESIRAJU, GR .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (21) :2311-2327

[15]

Enraf-Nonius, 1989, CAD 4 SOFTW VERS 5 0

[16] Water gelation by small organic molecules [J].

Estroff, LA ;

Hamilton, AD .

CHEMICAL REVIEWS, 2004, 104 (03) :1201-1217

[17] Crystal engineering of 2-D hydrogen bonded molecular networks based on the self-assembly of anionic and cationic modules [J].

Félix, O ;

Hosseini, MW ;

De Cian, A ;

Fischer, J .

CHEMICAL COMMUNICATIONS, 2000, (04) :281-282

[18] Molecular tectonics .3. The simultaneous use of H-bonding and coulomb interactions for the self-assembly of fumaric acid and cyclic bisamidine into one- and two-dimensional molecular networks [J].

Felix, O ;

Hosseini, MW ;

DeCian, A ;

Fischer, J .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (1-2) :102-104

[19] NRCVAX - AN INTERACTIVE PROGRAM SYSTEM FOR STRUCTURE-ANALYSIS [J].

GABE, EJ ;

LEPAGE, Y ;

CHARLAND, JP ;

LEE, FL ;

WHITE, PS .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1989, 22 :384-387

[20] ASYMMETRIC SYNTHESIS VIA REACTIONS IN CHIRAL CRYSTALS [J].

GREEN, BS ;

LAHAV, M ;

RABINOVICH, D .

ACCOUNTS OF CHEMICAL RESEARCH, 1979, 12 (06) :191-197

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