2D modeling of a defective PEMFC

被引:11
作者
Hinaje, M. [1 ]
Nguyen, D. A. [1 ]
Bonnet, C. [2 ]
Lapicque, F. [2 ]
Rael, S. [1 ]
Davat, B. [1 ]
机构
[1] GREEN INPL, 2 Ave Foret de Haye, F-5416 Vandoeuvre Les Nancy, France
[2] Nancy Univ, LRGP, CNRS, F-54000 Nancy, France
关键词
Defective cell; MEA degradation; Voltage drop; PEMFC pde modeling; EIS simulation; FUEL-CELLS; MEMBRANE;
D O I
10.1016/j.ijhydene.2011.05.146
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070305 [高分子化学与物理];
摘要
A dysfunctioning of the heart of the fuel cell might affect the whole system, and thus the demand of electric power. To be able to estimate the damage of the fuel cell, the default has to be detected precisely. As it is well known, the physico-chemical processes involved in proton exchange membrane fuel cell (PEMFC) are strongly coupled, as such that putting apart a phenomenon by experimental measurement can be quite difficult. To this end, simulations of an online or offline diagnosis, for instance by electrochemical impedance spectroscopy (EIS) method are interesting. It can help also to analyze what happens locally in the heart of cell. The main aim of the presented work is to highlight the interest of using PEMFC dynamic model as a diagnosis tool. To illustrate this potential, EIS method has been implemented in 2D dynamic single cell in both simulated cases of defective and healthy cells. Copyright (C) 2011, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:10884 / 10890
页数:7
相关论文
共 13 条
[1]
A MATHEMATICAL-MODEL OF THE SOLID-POLYMER-ELECTROLYTE FUEL-CELL [J].
BERNARDI, DM ;
VERBRUGGE, MW .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1992, 139 (09) :2477-2491
[2]
Impact of defective single cell on the operation of polymer electrolyte membrane fuel cell stack [J].
Hinaje, M. ;
Nguyen, D. ;
Rael, S. ;
Davat, B. ;
Bonnet, C. ;
Lapicque, F. .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2009, 34 (15) :6364-6370
[3]
Online humidification diagnosis of a PEMFC using a static DC-DC converter [J].
Hinaje, M. ;
Sadli, I. ;
Martin, J. -P. ;
Thounthong, P. ;
Rael, S. ;
Davat, B. .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2009, 34 (06) :2718-2723
[4]
Water transport coefficient distribution through the membrane in a polymer electrolyte fuel cell [J].
Liu, Fuqiang ;
Lu, Guoqiang ;
Wang, Chao-Yang .
JOURNAL OF MEMBRANE SCIENCE, 2007, 287 (01) :126-131
[5]
Nader Mahinpey, 2006, EFFECTS MASS TRANSFE
[6]
Neubrand W., 1999, MODELLBILDUNG SIMULA
[7]
Transient analysis of proton electrolyte membrane fuel cells (PEMFC) at start-up and failure [J].
Serincan, M. F. ;
Yesilyurt, S. .
FUEL CELLS, 2007, 7 (02) :118-127
[8]
Experimental and numerical studies of portable PEMFC stack [J].
Shimpalee, S. ;
Ohashi, M. ;
Van Zee, J. W. ;
Ziegler, C. ;
Stoeckmann, C. ;
Sadeler, C. ;
Hebling, C. .
ELECTROCHIMICA ACTA, 2009, 54 (10) :2899-2911
[9]
A two-dimensional computational model of a PEMFC with liquid water transport [J].
Siegel, NP ;
Ellis, MW ;
Nelson, DJ ;
von Spakovsky, MR .
JOURNAL OF POWER SOURCES, 2004, 128 (02) :173-184
[10]
POLYMER ELECTROLYTE FUEL-CELL MODEL [J].
SPRINGER, TE ;
ZAWODZINSKI, TA ;
GOTTESFELD, S .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1991, 138 (08) :2334-2342