Trapping the Parent Inorganic Ethylenes H2SiGeH2 and H2SiSnH2 in the Form of Stable Adducts at Ambient Temperature

被引：90

作者：

Al-Rafia, S. M. Ibrahim ^{[1
]}

Malcolm, Adam C. ^{[1
]}

McDonald, Robert ^{[1
]}

Ferguson, Michael J. ^{[1
]}

Rivard, Eric ^{[1
]}

机构：

[1] Univ Alberta, Dept Chem, Edmonton, AB T6G 2G2, Canada

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 36期

基金：

加拿大自然科学与工程研究理事会; 加拿大创新基金会;

关键词：

carbenes; dimetallenes; Group; 14; elements; hydrides; main-group elements; N-HETEROCYCLIC CARBENE; INFRARED-SPECTRA; DOUBLE-BONDS; SOLID NEON; CHEMISTRY; COMPLEXES; HYDRIDES; ANALOGS; SN; GE;

D O I：

10.1002/anie.201103576

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Putting on some weight: A series of stable adducts featuring the hitherto unknown mixed heavy ethylene analogues H2SiGeH2 and H 2SiSnH2 (see picture) were prepared using a versatile donor-acceptor method. © 2011 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：8354 / 8357

页数：4

共 59 条

[1] Intercepting low oxidation state main group hydrides with a nucleophilic N-heterocyclic olefin [J].

Al-Rafia, S. M. Ibrahim ;

Malcolm, Adam C. ;

Liew, Sean K. ;

Ferguson, Michael J. ;

McDonald, Robert ;

Rivard, Eric .

CHEMICAL COMMUNICATIONS, 2011, 47 (24) :6987-6989

[2] Stabilization of the Heavy Methylene Analogues, GeH2 and SnH2, within the Coordination Sphere of a Transition Metal [J].

Al-Rafia, S. M. Ibrahim ;

Malcolm, Adam C. ;

Liew, Sean K. ;

Ferguson, Michael J. ;

Rivard, Eric .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (04) :777-779

[3] Effect of the nature of metallocene complexes of group IV metals on their performance in catalytic ethylene and propylene polymerization [J].

Alt, HG ;

Köppl, A .

CHEMICAL REVIEWS, 2000, 100 (04) :1205-1221

[4] Infrared spectra of the novel Si2H2 and Si2H4 species and the SiH1,2,3 intermediates in solid neon, argon, and deuterium [J].

Andrews, L ;

Wang, XF .

JOURNAL OF PHYSICAL CHEMISTRY A, 2002, 106 (34) :7696-7702

[5] N-Heterocyclic Carbene Analogues with Low-Valent Group 13 and Group 14 Elements: Syntheses, Structures, and Reactivities of a New Generation of Multitalented Ligands [J].

Asay, Matthew ;

Jones, Cameron ;

Driess, Matthias .

CHEMICAL REVIEWS, 2011, 111 (02) :354-396

[6] Facile Synthesis of a Rare Chlorosilylene-BH3 Adduct [J].

Azhakar, Ramachandran ;

Tavcar, Gasper ;

Roesky, Herbert W. ;

Hey, Jakob ;

Stalke, Dietmar .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2011, (04) :475-477

[7] 4-COORDINATE AND 5-COORDINATE TIN(II) (STANNYLENE) COMPOUNDS - CRYSTAL AND MOLECULAR-STRUCTURES OF W(CO)5(SNCL2(OC4H8)) AND W(CO)5(SNCL2(OC4H8)2) [J].

BALCH, AL ;

ORAM, DE .

ORGANOMETALLICS, 1988, 7 (01) :155-158

[8]

Bonyhady SJ, 2010, NAT CHEM, V2, P865, DOI [10.1038/NCHEM.762, 10.1038/nchem.762]

[9]

Braunschweig H., 2010, ANGEW CHEM-GER EDIT, V122, P2085

[10] Synthesis and Structure of a Carbene-Stabilized π-Boryl Anion [J].

Braunschweig, Holger ;

Chiu, Ching-Wen ;

Radacki, Krzysztof ;

Kupfer, Thomas .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (11) :2041-2044

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