Nonrigid diastereomers: epimerization at chiral metal centers or chiral ligand conformations?

被引：36

作者：

Faller, JW ^{[1
]}

Parr, J ^{[1
]}

Lavoie, AR ^{[1
]}

机构：

[1] Yale Univ, Dept Chem, New Haven, CT 06520 USA

来源：

NEW JOURNAL OF CHEMISTRY | 2003年 / 27卷 / 06期

关键词：

D O I：

10.1039/b302054c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Variable temperature NMR studies of chiral metal complexes can reveal two diastereomers at lower temperatures. A caveat is presented regarding the possibility that chiral ligand conformations may be involved rather than epimeric chiral metal centers.

引用

页码：899 / 901

页数：3

共 46 条

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