Bidentate Lewis acids for organic synthesis

被引：26

作者：

Maruoka, K ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Sci, Dept Chem, Kyoto 6068502, Japan

来源：

CATALYSIS TODAY | 2001年 / 66卷 / 01期

关键词：

bidentate Lewis acids; asymmetric synthesis; organic synthesis;

D O I：

10.1016/S0920-5861(00)00602-7

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The chemistry of bidentate Lewis acids belongs to an unexplored field of science and has been only poorly studied so far. This review illustrates the design of several bidentate aluminum Leu is acids and their successful application to selective organic synthesis. The chemistry disclosed herein implies the vast potential of bidentate Lewis acids in other fields of chemistry including molecular recognition and asymmetric synthesis. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：33 / 45

页数：13

共 64 条

[1] Highly efficient alkylation of epoxides with R3Al/H2O systems based on the double activation of epoxy oxygens [J].

Abe, N ;

Hanawa, H ;

Maruoka, K ;

Sasaki, M ;

Miyashita, M .

TETRAHEDRON LETTERS, 1999, 40 (29) :5369-5372

[2] AN EXAMPLE OF ACETALDEHYDE BRIDGING 2 METAL ATOMS - SYNTHESES AND THE X-RAY CRYSTAL-STRUCTURE OF "MO2(CO)4(MU,ETA-2-MECHO)(ETA-C5H5)2 [J].

ADAMS, H ;

BAILEY, NA ;

GAUNTLETT, JT ;

WINTER, MJ .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1984, (20) :1360-1361

[3] COORDINATION AND INTERCONVERSION OF A KETONIC GROUPING BETWEEN ONE AND 2 TRANSITION-METAL ATOMS [J].

ADAMS, RD ;

CHEN, G ;

CHEN, LF ;

WU, WG ;

YIN, JG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (24) :9406-9408

[4] ALUMINUM ISOPROPOXIDE-TFA, A MODIFIED CATALYST FOR HIGHLY ACCELERATED MEERWEIN-PONNDORF-VERLEY (MPV) REDUCTION [J].

AKAMANCHI, KG ;

VARALAKSHMY, NR .

TETRAHEDRON LETTERS, 1995, 36 (20) :3571-3572

[5] Diisopropoxyaluminium trifluoroacetate/4-nitrobenzaldehyde - A new Oppenauer oxidation system for accelerated oxidation of secondary alcohols to the corresponding ketones [J].

Akamanchi, KG ;

Chaudhari, BA .

TETRAHEDRON LETTERS, 1997, 38 (39) :6925-6928

[6]

Akamanchi KG, 1997, SYNLETT, P371

[7]

[Anonymous], ZIEGLER CATALYSTS

[8]

[Anonymous], [No title captured]

[9]

[Anonymous], COMPREHENSIVE ORGANI

[10] Simultaneous coordination and double activation phenomena of carbonyl and epoxy oxygens by bis-titanium reagent as a bidentate Lewis acid catalyst [J].

Asao, N ;

Kii, S ;

Hanawa, H ;

Maruoka, K .

TETRAHEDRON LETTERS, 1998, 39 (22) :3729-3732

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