Photocatalytic labyrinth flow reactor with immobilized P25TiO2 bed for removal of phenol from water

被引:73
作者
Grzechulska, J [1 ]
Morawski, AW [1 ]
机构
[1] Tech Univ Szczecin, Inst Chem & Environm Engn, PL-70322 Szczecin, Poland
关键词
photocatalysis; titanium dioxide; activity decrease;
D O I
10.1016/S0926-3373(03)00265-0
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The photocatalytic oxidation of phenol in water in the labyrinth flow reactor with immobilized catalyst bed was investigated. Degussa P25 was used as a photocatalyst. It was observed that the photocatalytic material considerably losses its activity during repeated test trials for the high initial phenol concentration of 300 mg/dm(3). Diffuse reflectance UV-Vis analysis showed shift in the threshold absorption value and corresponding band gap energy of the photocatalytic material. FTIR analysis revealed the carbon deposits on the catalyst surface. These two factors are considered to be responsible for the activity decrease. (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码:415 / 419
页数:5
相关论文
共 18 条
  • [1] Photocatalysis in water environments using artificial and solar light
    Alfano, OM
    Bahnemann, D
    Cassano, AE
    Dillert, R
    Goslich, R
    [J]. CATALYSIS TODAY, 2000, 58 (2-3) : 199 - 230
  • [2] Advanced oxidation processes (AOP) for water purification and recovery
    Andreozzi, R
    Caprio, V
    Insola, A
    Marotta, R
    [J]. CATALYSIS TODAY, 1999, 53 (01) : 51 - 59
  • [3] [Anonymous], US EPA PUBL
  • [4] Photocatalytic degradation for environmental applications - a review
    Bhatkhande, DS
    Pangarkar, VG
    Beenackers, AACM
    [J]. JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY, 2002, 77 (01) : 102 - 116
  • [5] BLAKE DM, 1997, NERLTP43022197 GOLD
  • [6] Heterogeneous photocatalytic oxidation of benzene, toluene, cyclohexene and cyclohexane in humidified air:: comparison of decomposition behavior on photoirradiated TiO2 catalyst
    Einaga, H
    Futamura, S
    Ibusuki, T
    [J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 2002, 38 (03) : 215 - 225
  • [7] Comparison of different advanced oxidation processes for phenol degradation
    Esplugas, S
    Giménez, J
    Contreras, S
    Pascual, E
    Rodríguez, M
    [J]. WATER RESEARCH, 2002, 36 (04) : 1034 - 1042
  • [8] Preparation and characterization of TiO2 photocatalysts supported on various rigid supports (glass, quartz and stainless steel). Comparative studies of photocatalytic activity in water purification
    Fernandez, A
    Lassaletta, G
    Jimenez, VM
    Justo, A
    GonzalezElipe, AR
    Herrmann, JM
    Tahiri, H
    AitIchou, Y
    [J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 1995, 7 (1-2) : 49 - 63
  • [9] Heterogeneous photocatalysis: fundamentals and applications to the removal of various types of aqueous pollutants
    Herrmann, JM
    [J]. CATALYSIS TODAY, 1999, 53 (01) : 115 - 129
  • [10] Characterization and photocatalytic activity in aqueous medium of TiO2 and Ag-TiO2 coatings on quartz
    Herrmann, JM
    Tahiri, H
    AitIchou, Y
    Lassaletta, G
    GonzalezElipe, AR
    Fernandez, A
    [J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 1997, 13 (3-4) : 219 - 228