Metathesis in the presence of a transition metal alkyne complex

被引：18

作者：

Burlison, JA ^{[1
]}

Gray, JM ^{[1
]}

Young, DGJ ^{[1
]}

机构：

[1] Univ Tennessee, Dept Chem, Knoxville, TN 37996 USA

来源：

TETRAHEDRON LETTERS | 2001年 / 42卷 / 32期

关键词：

cyclic alkene; metathesis; dicobalthexacarbonyl alkyne complex;

D O I：

10.1016/S0040-4039(01)01017-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A ring closing metathesis approach to medium sized rings is described. The methodology succeeds in the presence of a transition metal alkyne complex. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：5363 / 5365

页数：3

共 34 条

[1] Stereoselective synthesis of a functionalised bicyclic core of neocarzinostatin and kedarcidin chromophores [J].

Caddick, S ;

Delisser, VM .

TETRAHEDRON LETTERS, 1997, 38 (13) :2355-2358

[2] SMI2-MEDIATED CYCLIZATION OF VINYL RADICALS [J].

CAPELLA, L ;

MONTEVECCHI, PC .

TETRAHEDRON LETTERS, 1994, 35 (45) :8445-8448

[3] PROTECTION OF HYDROXYL GROUPS AS TERT-BUTYLDIMETHYLSILYL DERIVATIVES [J].

COREY, EJ ;

VENKATESWARLU, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1972, 94 (17) :6190-+

[4]

DARRESH S, 1991, CAN J CHEM, V69, P712

[5] ADDITION OF ALLYLMAGNESIUM BROMIDE TO HINDERED KETONES [J].

DEMEESTER, WA ;

FUSON, RC .

JOURNAL OF ORGANIC CHEMISTRY, 1965, 30 (12) :4332-+

[6] A concise total synthesis of dactylol via ring closing metathesis [J].

Furstner, A ;

Langemann, K .

JOURNAL OF ORGANIC CHEMISTRY, 1996, 61 (25) :8746-8749

[7] Cycloheptyne-cobalt complexes via allylation of stabilized γ-carbonyl cations [J].

Green, JR .

CHEMICAL COMMUNICATIONS, 1998, (16) :1751-1752

[8] ACETYLENIC DICOBALT HEXACARBONYLS - ORGANOMETALLIC COMPOUNDS DERIVED FROM ALKYNES AND DICOBALT OCTACARBONYL [J].

GREENFIELD, H ;

STERNBERG, HW ;

FRIEDEL, RA ;

WOTIZ, JH ;

MARKBY, R ;

WENDER, I .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1956, 78 (01) :120-124

[9] MECHANISM OF THE 1,3-SIGMATROPIC SHIFT OF 2-VINYLCYCLOBUTANOL ALKOXIDES [J].

HARRIS, NJ ;

GAJEWSKI, JJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (14) :6121-6129

[10] ETHYNYL-TERMINATED POLYARYLATES - SYNTHESIS AND CHARACTERIZATION [J].

HAVENS, SJ ;

HERGENROTHER, PM .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1984, 22 (11) :3011-3025

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