Photocatalytic H2 evolution under visible light irradiation on AgIn5S8 photocatalyst

被引:81
作者
Chen, Di [1 ]
Ye, Jinhua [1 ]
机构
[1] Natl Inst Mat Sci, Photo Catalyt Mat Ctr, Tsukuba, Ibaraki 3050047, Japan
关键词
chalcogenides; metals; chemical synthesis; X-ray diffraction;
D O I
10.1016/j.jpcs.2007.07.059
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new visible-light-driven photocatalyst AgIn5S8 was prepared by a simple two-step process, which involves the first co-precipitation process at room temperature and subsequently heat-treatment process at 750 degrees C under pure argon flow protection. The obtained AgIn5S8 sample showed high activity for the evolution of hydrogen under visible light irradiation 420 nm) from aqueous solution containing S2- and SO32 ions as sacrificial electron donors. It was found that several experimental parameters, such as the concentration of sacrificial reagents and the loading of Pt co-catalyst, play important roles on the evolution rate of H-2 under visible light irradiation. (c) 2007 Elsevier Ltd. All rights reserved.
引用
收藏
页码:2317 / 2320
页数:4
相关论文
共 26 条
[11]   AgInZn7S9 solid solution photocatalyst for H2 evolution from aqueous solutions under visible light irradiation [J].
Kudo, A ;
Tsuji, I ;
Kato, H .
CHEMICAL COMMUNICATIONS, 2002, (17) :1958-1959
[12]   Optical absorption of Co2+ in AgIn5S8 and CuIn5S8 spinel crystals [J].
Lee, SJ ;
Kim, JE ;
Park, HY .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 2003, 42 (6A) :3337-3339
[13]   Photocatalytic water reduction under visible light on a novel ZnIn2S4 catalyst synthesized by hydrothermal method [J].
Lei, ZB ;
You, WS ;
Liu, MY ;
Zhou, GH ;
Takata, T ;
Hara, M ;
Domen, K ;
Li, C .
CHEMICAL COMMUNICATIONS, 2003, (17) :2142-2143
[14]  
PLESOV V, 1986, SEMICONDUCTOR PHOTOE
[15]   PHOTOCHEMICAL HYDROGEN-PRODUCTION WITH PLATINIZED SUSPENSIONS OF CADMIUM-SULFIDE AND CADMIUM ZINC-SULFIDE MODIFIED BY SILVER SULFIDE [J].
REBER, JF ;
RUSEK, M .
JOURNAL OF PHYSICAL CHEMISTRY, 1986, 90 (05) :824-834
[16]   NEW CHALCOGENIDES OF TYPE M+0.5IN0.5M23+X4 [J].
ROBBINS, M ;
MIKSOVSKY, MA .
MATERIALS RESEARCH BULLETIN, 1971, 6 (05) :359-+
[17]   COMMENTS ON SYSTEM AG2S-IN2S3 [J].
ROTH, RS ;
PARKER, HS ;
BROWER, WS .
MATERIALS RESEARCH BULLETIN, 1973, 8 (03) :333-338
[18]   Alternate synthetic strategy for the preparation of CdS nanoparticles and its exploitation for water splitting [J].
Sathish, M. ;
Viswanathan, B. ;
Viswanath, R. P. .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2006, 31 (07) :891-898
[19]   RuO2-loaded β-Ge3N4 as a non-oxide photocatalyst for overall water splitting [J].
Sato, J ;
Saito, N ;
Yamada, Y ;
Maeda, K ;
Takata, T ;
Kondo, JN ;
Hara, M ;
Kobayashi, H ;
Domen, K ;
Inoue, Y .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (12) :4150-4151
[20]   Photocatalytic activity for water decomposition of indates with octahedrally coordinated d10 configuration.: I.: Influences of preparation conditions on activity [J].
Sato, J ;
Saito, N ;
Nishiyama, H ;
Inoue, Y .
JOURNAL OF PHYSICAL CHEMISTRY B, 2003, 107 (31) :7965-7969