Unusual electrochemical properties of the inclusion complexes of ferrocenium and cobaltocenium with cucurbit[7]uril

被引：128

作者：

Ong, W

Kaifer, AE ^{[1
]}

机构：

[1] Univ Miami, Ctr Supramol Sci, Coral Gables, FL 33124 USA

[2] Univ Miami, Dept Chem, Coral Gables, FL 33124 USA

来源：

ORGANOMETALLICS | 2003年 / 22卷 / 21期

关键词：

D O I：

10.1021/om030305x

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Ferrocenium and cobaltocenium form highly stable 1:1 inclusion complexes with the host cucurbit[7]-uril. From electronic absorption spectroscopic data the association equilibrium constants for both complexes were found to be larger than 10(6) L/mol. The electrochemical reduction of either guest leads to a modest loss in binding affinity.

引用

页码：4181 / 4183

页数：3

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