Synthesis and characterization of hydroxy-functionalized models for the active site in Fe-only-hydrogenases

被引：36

作者：

Apfel, Ulf-Peter

Halpin, Yvonne

Goerls, Helmar

Vos, Johannes G.

Schweizer, Bernd

Linti, Gerald

Weigand, Wolfgang

机构：

[1] Univ Jena, D-07743 Jena, Germany

[2] Dublin City Univ, Sch Chem Sci, Dublin 9, Ireland

[3] ETH, Organ Chem Lab, CH-8093 Zurich, Switzerland

[4] Univ Heidelberg, D-69120 Heidelberg, Germany

来源：

CHEMISTRY & BIODIVERSITY | 2007年 / 4卷 / 09期

关键词：

D O I：

10.1002/cbdv.200790171

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

The reactions of DL-1,4-disulfanylbutane-2,3-diol and 1,3-disulfanylpropan-2-ol with dodecacarbonyltriiron have been investigated. As main products, the iron complexes I and 2 were isolated and characterized by spectroscopic methods, as well as single crystal X-ray analysis. Additionally, the unusually large bond angles in the dithiolato bridge was investigated via density-functional theory (DFT) calculations. Moreover, the electrochemical features have been studied by cyclic voltammetry.

引用

页码：2138 / 2148

页数：11

共 26 条

[1] SIR97:: a new tool for crystal structure determination and refinement [J].