Chiral N-heterocyclic carbene-Pd(0)-catalyzed asymmetric diamination of conjugated dienes and triene

被引：74

作者：

Xu, Liang ^{[1
]}

Shi, Yian ^{[1
]}

机构：

[1] Colorado State Univ, Dept Chem, Ft Collins, CO 80523 USA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2008年 / 73卷 / 02期

关键词：

D O I：

10.1021/jo702167u

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] Studies show that a variety of conjugated dienes and triene can be enantioselectively diaminated using di-tert-butyldiaziridinone as nitrogen source and chiral N-heterocyclic carbene-Pd(0) complex as catalyst in good enantio selectivity (62-91% ee) with high regio- and diastereoselectivity.

引用

页码：749 / 751

页数：3

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