New chiral NMR shift reagent for α-amino acids and N-protected oligopeptides in aqueous solution

被引：16

作者：

Watanabe, M ^{[1
]}

Hasegawa, T ^{[1
]}

Miyake, H ^{[1
]}

Kojima, Y ^{[1
]}

机构：

[1] Osaka City Univ, Dept Chem, Grad Sch Sci, Sumiyoshi Ku, Osaka 5588585, Japan

来源：

CHEMISTRY LETTERS | 2001年 / 01期

关键词：

D O I：

10.1246/cl.2001.4

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A europium(III) complex with a new chiral ligand, N,N-bis[2-{N-methyl((1S)-1-carboxy-3-methyl) butylamino}ethyl]-glycine, is described as a new chiral shift reagent for cr-amino acids and N-acyl-oligopeptides in aqueous solutions without signal broadening on high resolution NMR spectroscopy. In addition, the molecular structure of lanthanum(III) complex with this ligand is revealed by X-ray crystallography.

引用

页码：4 / 5

页数：2

共 18 条

[1] A novel compound in the lanthanide(III) DOTA series. X-ray crystal and molecular structure of the complex Na[La(DOTA)La(HDOTA)]center dot 10H(2)O
Aime, S
Barge, A
Benetollo, F
Bombieri, G
Botta, M
Uggeri, F
[J]. INORGANIC CHEMISTRY, 1997, 36 (19) : 4287 - 4289
[2] CIRCULARLY POLARIZED LUMINESCENCE STUDIES OF THE TERNARY COMPLEXES FORMED BETWEEN TERBIUM(III), PYRIDINE-2,6-DICARBOXYLIC ACID, AND AMINO-ACIDS
BRITTAIN, HG
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (11) : 3693 - 3698
[3] CHEN SY, 1989, SCI CHINA SER B, V32, P918
[4] SOLUTION STRUCTURE AND DYNAMICS OF LANTHANIDE COMPLEXES OF THE MACROCYCLIC POLYAMINO CARBOXYLATE DTPA-DIEN - NMR-STUDY AND CRYSTAL-STRUCTURES OF THE LANTHANUM(III) AND EUROPIUM(III) COMPLEXES
FRANKLIN, SJ
RAYMOND, KN
[J]. INORGANIC CHEMISTRY, 1994, 33 (25) : 5794 - 5804
[5] CRYSTAL AND MOLECULAR-STRUCTURE OF DECACOORDINATE COMPOUND ((HYDROXYETHYL)ETHYLENEDIAMINETRIACETATO)DIAQUOLANTHANUM(III) TRIHYDRATE
FULLER, CC
MOLZAHN, DK
JACOBSON, RA
[J]. INORGANIC CHEMISTRY, 1978, 17 (08) : 2138 - 2143
[6] A europium(III)-N,N,N',N'-tetrakis(2-pyridylmethyl)-(R)-propylenediamine complex as a new chiral lanthanide NMR shift reagent for aqueous neutral solution
Hazama, R
Umakoshi, K
Kabuto, C
Kabuto, K
Sasaki, Y
[J]. CHEMICAL COMMUNICATIONS, 1996, (01) : 15 - 16
[7] HULST R, 1994, J ORG CHEM, V59, P745
[8] YTTRIUM(III) AND LANTHANUM(III) COMPLEXES OF A 15-MEMBERED MACROCYCLE WITH 3 PENDANT CARBOXYMETHYL GROUPS
INOUE, MB
INOUE, M
FERNANDO, Q
[J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1994, 50 : 1037 - 1040
[9] THE EUROPIUM(III) (R)-PROPYLENEDIAMINETETRA-ACETATE ION - A PROMISING CHIRAL SHIFT-REAGENT FOR H-1-NMR SPECTROSCOPY IN AQUEOUS-SOLUTION
KABUTO, K
SASAKI, Y
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1984, (05) : 316 - 318
[10] HIGHLY CONSISTENT CORRELATION BETWEEN ABSOLUTE-CONFIGURATION OF ALPHA-AMINO-ACIDS AND THEIR SHIFT INDUCED BY THE NMR CHIRAL SHIFT-REAGENT PROPYLENEDIAMINETETRAACETATOEUROPIUM(III) IN AQUEOUS-SOLUTION
KABUTO, K
SASAKI, Y
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (09) : 670 - 671

← 1 2 →