Transient photoconductivity in a film of ladder-type poly-phenylene:: failure of the Onsager approach

被引：14

作者：

Weiter, M

Bässler, H

Gulbinas, V

Scherf, U

机构：

[1] Univ Marburg, Inst Phys Macromol & Nucl Chem, D-35032 Marburg, Germany

[2] Inst Phys, LT-2600 Vilnius, Lithuania

[3] Berg Univ Wuppertal, Dept Chem, D-42119 Wuppertal, Germany

[4] Brno Univ Technol, Fac Chem, Brno 61200, Czech Republic

来源：

CHEMICAL PHYSICS LETTERS | 2003年 / 379卷 / 1-2期

关键词：

D O I：

10.1016/j.cplett.2003.08.043

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

By comparing the field dependent evolution of the transient absorption of geminate pairs generated of singlet excitons in a film of ladder-type poly-phenylene and the field dependent transient photocurrent it is argued that the rate limiting step for photoionization is the initial field assisted dissociation into geminately bounded electron-hole pairs rather than its ultimate escape from the coulombic well. (C) 2003 Elsevier B.V. All rights reserved.

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页码：177 / 182

页数：6

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