Application of basic zeolites in the decomposition reaction of 2-methyl-3-butyn-2-ol and the isomerization of 3-carene

被引：33

作者：

Meyer, U ^{[1
]}

Hoelderich, WF ^{[1
]}

机构：

[1] Aachen Tech Univ, Rhein Westfal TH Aachen, Dept Chem Technol & Heterogeneous Catalysis, D-52074 Aachen, Germany

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1999年 / 142卷 / 02期

关键词：

basic zeolite; base catalysis; solid base; 2-methyl-3-butyn-2-ol; carene;

D O I：

10.1016/S1381-1169(98)00289-1

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Basic zeolite catalysts can be generated via ion exchange or via impregnation with alkali metals and alkali metal acetates following different methods. The decomposition of 2-methyl-3-butyn-2-ol and the isomerization reaction of 3-carene to 2-carene have been studied in the gas phase over various basic zeolites to investigate their value as test reactions for basic properties of zeolites. (C) 1999 Elsevier Science B.V. All rights reserved.

引用

页码：213 / 222

页数：10

共 14 条

[1] HYDROBORATION OF TERPENES .3. ISOMERIZATION OF (+)-3-CARENE TO (+)-2-CARENE . HYDROBORATION OF (+)-2-CARENE (DELTA4-CARENE) . NUCLEAR MAGNETIC RESONANCE SPECTRA WITH ABSOLUTE CONFIGURATIONAL AND CONFORMATIONAL ASSIGNMENTS FOR 2-CARANOLS AND 2-CARANONES [J].