Sodium trifluoroacetate: an efficient precursor for the trifluoromethylation of aldehydes

被引：33

作者：

Chang, Y ^{[1
]}

Cai, C ^{[1
]}

机构：

[1] Nanjing Univ Sci & Technol, Sch Chem Engn, Nanjing 210094, Peoples R China

来源：

TETRAHEDRON LETTERS | 2005年 / 46卷 / 18期

关键词：

trifluoromethylation; nucleophilic addition; sodium trifluoroacetate; aldehyde;

D O I：

10.1016/j.tetlet.2005.03.072

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In a convenient and efficient procedure, the nucleophilic trifluoromethylation of aldehydes With sodium trifluoroacetate was achieved, using copper(I) halides as the catalyst. (c) 2005 Elsevier Ltd. All rights reserved.

引用

页码：3161 / 3164

页数：4

共 23 条

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[22] Cesium fluoride catalyzed trifluoromethylation of esters, aldehydes, and ketones with (trifluoromethyl)trimethylsilane
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[J]. JOURNAL OF ORGANIC CHEMISTRY, 1999, 64 (08) : 2873 - 2876
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