Synthesis and characterization of two metal phosphonates with 3D structures:: CuI2CuII[(3-C5H4N)CH(OH)PO3]2 and Zn[(3-C5H4N)CH(OH)PO3]

被引：24

作者：

Cao, DK ^{[1
]}

Liu, YJ ^{[1
]}

Song, Y ^{[1
]}

Zheng, LM ^{[1
]}

机构：

[1] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China

来源：

NEW JOURNAL OF CHEMISTRY | 2005年 / 29卷 / 05期

关键词：

D O I：

10.1039/b416276e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two novel phosphonate compounds, (Cu2CuII)-Cu-I[(3-C5H4N)CH(OH)PO3](2) (1) and Zn[(3-C5H4N)CH(OH)PO3] ( 2), have been synthesized by solvothermal reactions of the corresponding metal salts with [hydroxy(3-pyridyl)methyl]phosphonic acid. Compound 1 contains inorganic chains made up of (CuO4)-O-II planes and CPO3 tetrahedra through corner sharing. These chains are connected by (CuON)-O-I units through pyridine rings, forming a 3D open framework structure. Compound 2 adopts a new type of pillared layered structure. The inorganic layer contains 8- and 16-membered rings made up of ZnO3N and CPO3 tetrahedra. Pyridine rings are fixed between the inorganic layers through covalent bonds. The magnetic study shows that weak ferromagnetic interactions are mediated between magnetic centers in compound 1.

引用

页码：721 / 725

页数：5

共 45 条

[11] SHAPE-SELECTIVE INTERCALATION REACTIONS OF LAYERED ZINC AND COBALT PHOSPHONATES [J].

CAO, G ;

MALLOUK, TE .

INORGANIC CHEMISTRY, 1991, 30 (07) :1434-1438

[12] SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF A HOMOLOGOUS SERIES OF DIVALENT-METAL PHOSPHONATES, MII(O3PR).H2O AND MII(HO3PR)2 [J].

CAO, G ;

LEE, H ;

LYNCH, VM ;

MALLOUK, TE .

INORGANIC CHEMISTRY, 1988, 27 (16) :2781-2785

[13] LAYERED METAL PHOSPHATES AND PHOSPHONATES - FROM CRYSTALS TO MONOLAYERS [J].

CAO, G ;

HONG, HG ;

MALLOUK, TE .

ACCOUNTS OF CHEMICAL RESEARCH, 1992, 25 (09) :420-427

[14] NCHU-3: A crystalline inorganic-organic hybrid molecular sieve with extra-large cages [J].

Cheng, CY ;

Fu, SJ ;

Yang, CJ ;

Chen, WH ;

Lin, KJ ;

Lee, GH ;

Wang, Y .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (17) :1937-1940

[15]

Clearfield A, 1998, PROG INORG CHEM, V47, P371

[16] Azacrown ether pillared layered zirconium phosphonates and the crystal structure of N,N′-bis(phosphonomethyl)-1,10-diaza-18-crown-6 [J].

Clearfield, A ;

Poojary, DM ;

Zhang, BL ;

Zhao, BY ;

Derecskei-Kovacs, A .

CHEMISTRY OF MATERIALS, 2000, 12 (09) :2745-2752

[17] SYNTHESIS AND CRYSTAL-STRUCTURE OF ZN(O3PC2H4NH2), THE FIRST FUNCTIONALIZED ZEOLITE-LIKE PHOSPHONATE [J].

DRUMEL, S ;

JANVIER, P ;

DENIAUD, D ;

BUJOLI, B .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (10) :1051-1052

[18] SYNTHESIS, STRUCTURE, AND REACTIVITY OF SOME FUNCTIONALIZED ZINC AND COPPER(II) PHOSPHONATES [J].

DRUMEL, S ;

JANVIER, P ;

BARBOUX, P ;

BUJOLIDOEUFF, M ;

BUJOLI, B .

INORGANIC CHEMISTRY, 1995, 34 (01) :148-156

[19] Synthesis and characterization of [Mo7O16(O3PCH2PO3)3]:8- -: A mixed-valent polyoxomolybdenum diphosphonate anion with octahedrally and tetrahedrally coordinated molybdenum [J].

Dumas, E ;

Sassoye, C ;

Smith, KD ;

Sevov, SC .

INORGANIC CHEMISTRY, 2002, 41 (15) :4029-4032

[20] Microporous solids:: From organically templated inorganic skeletons to hybrid frameworks ... ecumenism in chemistry [J].

Férey, G .

CHEMISTRY OF MATERIALS, 2001, 13 (10) :3084-3098

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