Palladium-catalyzed Direct C-H Bond Arylation of Simple Arenes with Aryltrimethylsilanes

被引：49

作者：

Funaki, Kenji ^{[1
]}

Kawai, Hiroshi ^{[1
]}

Sato, Tetsuo ^{[1
,2
]}

Oi, Shuichi ^{[1
,2
]}

机构：

[1] Tohoku Univ, Grad Sch Engn, Dept Appl Chem, Aoba Ku, Sendai, Miyagi 9808579, Japan

[2] Tohoku Univ, Environm Conservat Res Inst, Aoba Ku, Sendai, Miyagi 9808579, Japan

来源：

CHEMISTRY LETTERS | 2011年 / 40卷 / 09期

关键词：

CROSS-COUPLING REACTIONS; HETEROAROMATIC-COMPOUNDS; ARYL CHLORIDES; ACTIVATION; FUNCTIONALIZATION; REAGENTS; COMPLEXES; CLEAVAGE; NICKEL; ACIDS;

D O I：

10.1246/cl.2011.1050

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Direct C-H bond arylation of arenes with aryltrimethylsilanes catalyzed by PdCl2 in the presence of CuCl2 as an oxidant has been developed. In addition to the role as the oxidant, CuCl2 is found to be necessary for the selective cross-coupling reaction.

引用

页码：1050 / 1052

页数：3

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