Double direct templating of periodically nanostructured ZnS hollow microspheres

被引：95

作者：

Wolosiuk, A

Armagan, O

Braun, PV

机构：

[1] Univ Illinois, Dept Mat Sci & Engn, Beckman Inst, Urbana, IL 61801 USA

[2] Univ Illinois, Frederick Seitz Mat Res Lab, Urbana, IL 61801 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 47期

关键词：

D O I：

10.1021/ja054927g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We introduce a "double direct templating" method for obtaining hollow microspheres with periodically nanostructured walls. Silica or polystyrene colloids are dispersed in a self-assembled hexagonal lyotropic liquid crystal containing precursors for ZnS. The semiconductor ZnS mineralizes on the surface of the colloid, expressing a pore morphology that is a copy of the structure of the liquid crystal. After etching of the sacrificial colloids, hollow capsules with templated and uniform mesoporous shells are obtained. Copyright © 2005 American Chemical Society.

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页码：16356 / 16357

页数：2

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