Enantio- and diastereocontrolled synthesis of an angular triquinane sesquiterpene (+)-arnicenone

被引：27

作者：

Iura, Y ^{[1
]}

Sugahara, T ^{[1
]}

Ogasawara, K ^{[1
]}

机构：

[1] Tohoku Univ, Inst Pharmaceut, Sendai, Miyagi 9808578, Japan

来源：

ORGANIC LETTERS | 2001年 / 3卷 / 02期

关键词：

D O I：

10.1021/ol006922o

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] (+)-Arnicenone, a sesquiterpene of an angular triquinane isolated from Arnica plants, has been synthesized for the first time in an enantiocontrolled manner from a synthetic equivalent of chiral 2-hydroxymethylcyclopentadienone to determine the absolute configuration of the natural product as 1R,3aR,5aS,8aR.

引用

页码：291 / 293

页数：3

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