Mechanochemical transformations and reactivity in copper sulphides

被引：28

作者：

Baláz, P

Takacs, L

Boldizárová, E

Godocíková, E

机构：

[1] Slovak Acad Sci, Inst Geotech, Kosice 04353, Slovakia

[2] Univ Maryland Baltimore Cty, Dept Phys, Baltimore, MD 21250 USA

来源：

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS | 2003年 / 64卷 / 08期

基金：

美国国家科学基金会;

关键词：

chalcogenides;

D O I：

10.1016/S0022-3697(03)00189-6

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Mechanochemical transformations of copper sulphides were induced by processing in a Fritsch Pulverisette 6 planetary mill. The main changes during high-energy milling are the phase transformations of the djurleite (Cu194S)-S-. which is the main phase in a starting material. Digenite, which is in fact a group of copper sulphides (Cu1.80S, Cu1.765S and Cu9-xS5, respectively) together with chalcocite (Cu1.96S and Cu2S, respectively) are the main phases among the mechanochemical products. The reactivity of the products is compared to their physico-chemical transformations during high energy milling. (C) 2003 Elsevier Science Ltd. All rights reserved.

引用

页码：1413 / 1417

页数：5

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