Assembly of a porous three-dimensional coordination polymer:: Crystal structure of {[La2(adipate)3(H2O)4]6H2O}n

被引：191

作者：

Kiritsis, V ^{[1
]}

Michaelides, A

Skoulika, S

Golhen, S

Ouahab, L

机构：

[1] Univ Ioannina, Dept Chem, GR-45110 Ioannina, Greece

[2] Univ Rennes 1, Chim Solide & Inorgan Mol Lab, UMR 6511, F-35042 Rennes, France

来源：

INORGANIC CHEMISTRY | 1998年 / 37卷 / 13期

关键词：

D O I：

10.1021/ic980014u

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The structure and dehydration behavior of the porous 3D coordination polymer {[La-2(adipate)(3)(H2O)(4)]6H(2)O}(n) are described. Each La3+ is coordinated by nine oxygen atoms belonging to five carboxylate ligands and to two water molecules. Large infinite interconnected channels filled with hydrogen-bonded water molecules are formed in the structure. Upon heating, this compound transforms reversibly into a nonporous lower hydrate.

引用

页码：3407 / +

页数：5

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