Energy landscape and rigidity

被引:120
作者
Naumis, GG [1 ]
机构
[1] Univ Nacl Autonoma Mexico, Inst Fis, Mexico City 01000, DF, Mexico
来源
PHYSICAL REVIEW E | 2005年 / 71卷 / 02期
关键词
D O I
10.1103/PhysRevE.71.026114
中图分类号
O35 [流体力学]; O53 [等离子体物理学];
学科分类号
070204 ; 080103 ; 080704 ;
摘要
The effects of floppy modes in the thermodynamical properties of a system are studied. From thermodynamical arguments, we deduce that floppy modes are not at zero frequency and thus a modified Debye model is used to take into account this effect. The model predicts a deviation from the Debye law at low temperatures. Then, the connection between the topography of the energy landscape, the topology of the phase space, and the rigidity of a glass is explored. As a result, we relate the number of constraints and floppy modes to the statistics of the landscape. We apply these ideas to a simple model for which we provide an approximate expression for the number of energy basins as a function of the rigidity. This helps to understand certain features of the glass transition, like the jump in the specific heat or the reversible window observed in chalcogenide glasses.
引用
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页数:7
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