Recent advances in the synthesis of 1,3-diketones

被引：84

作者：

Kel'in, AV ^{[1
]}

机构：

[1] GLSynth Inc, Worcester, MA 01605 USA

来源：

CURRENT ORGANIC CHEMISTRY | 2003年 / 7卷 / 16期

关键词：

D O I：

10.2174/1385272033486233

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The most recent achievements in the construction of the 1,3-diketone moiety are reviewed. Though both classical and modern approaches to the synthesis of 1,3-diketones are compared and analyzed in terms of efficiency, functional group compatibility, regio-, and stereoselectivity, main attention is paid to recently discovered methods based on rearrangements and concerted mechanisms. Molecular structure investigations, appearance in nature, and biological activity of 1,3-diketones are also briefly reviewed.

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页码：1691 / 1711

页数：21

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