A Large-Bandgap Conjugated Polymer for Versatile Photovoltaic Applications with High Performance

被引:1077
作者
Zhang, Maojie [1 ,2 ]
Guo, Xia [1 ,2 ]
Ma, Wei [3 ,4 ]
Ade, Harald [4 ]
Hou, Jianhui [1 ]
机构
[1] Chinese Acad Sci, Inst Chem, State Key Lab Polymer Phys & Chem, Beijing 100190, Peoples R China
[2] Soochow Univ, Coll Chem Chem Engn & Mat Sci, Lab Adv Optoelect Mat, Suzhou 215123, Peoples R China
[3] Xi An Jiao Tong Univ, State Key Lab Mech Behav Mat, Xian 710049, Peoples R China
[4] N Carolina State Univ, Dept Phys, Raleigh, NC 27695 USA
关键词
large bandgap; molecular energy levels; polymer solar cells; semitransparent; POWER CONVERSION EFFICIENCY; MOLECULAR-ENERGY LEVEL; OPEN-CIRCUIT VOLTAGE; SOLAR-CELLS; FLUORINE SUBSTITUENTS; TANDEM POLYMER; SIDE-CHAINS; DESIGN; DONOR; MORPHOLOGY;
D O I
10.1002/adma.201502110
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new copolymer PM6 based on fluorothienyl-substituted benzodithiophene is synthesized and characterized. The inverted polymer solar cells based on PM6 exhibit excellent performance with Voc of 0.98 V and power conversion efficiency (PCE) of 9.2% for a thin-film thickness of 75 nm. Furthermore, the single-junction semitransparent device shows a high PCE of 5.7%. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:4655 / 4660
页数:6
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