Precise Synthesis of Molecularly Defined Oligomers and Polymers by Orthogonal Iterative Divergent/Convergent Approaches

被引：91

作者：

Binauld, Sandra ^{[5
]}

Damiron, Denis

Connal, Luke A. ^{[1
,2
,3
,4
]}

Hawker, Craig J. ^{[1
,2
,3
,4
]}

Drockenmuller, Eric ^{[6
]}

机构：

[1] Univ Calif Santa Barbara, Dept Mat, Santa Barbara, CA 93106 USA

[2] Univ Calif Santa Barbara, Dept Chem, Santa Barbara, CA 93106 USA

[3] Univ Calif Santa Barbara, Dept Biochem, Santa Barbara, CA 93106 USA

[4] Univ Calif Santa Barbara, Mat Res Lab, Santa Barbara, CA 93106 USA

[5] Univ New S Wales, Sch Chem Engn, Ctr Adv Macromol Design, Unsw Sydney, NSW 2052, Australia

[6] Univ Lyon 1, Ingn Mat Polymeres UMR CNRS 5223, Inst Univ France, F-69622 Villeurbanne, France

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 2011年 / 32卷 / 02期

基金：

美国国家科学基金会; 澳大利亚研究理事会;

关键词：

iterative divergent/convergent growth; macrocycles; oligomers; orthogonal reactions; telechelics; LINEAR ALIPHATIC-COMPOUNDS; LIQUID-PHASE SYNTHESIS; LONG-CHAIN ALKANES; SOLID-PHASE; CLICK CHEMISTRY; RAPID SYNTHESIS; CONJUGATED OLIGOMERS; EXPONENTIAL-GROWTH; SHAPE-PERSISTENT; FUNCTIONAL OLIGOTHIOPHENES;

D O I：

10.1002/marc.201000548

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The synthesis of perfectly defined (macro)molecules has been a constant challenge for polymer and organic chemists. This paper highlights the main applications of the iterative divergent/convergent approach for the synthesis of discrete mass oligomers and polymers. We will discuss the orthogonal deprotection and coupling strategies involved in this powerful strategy where chain length doubles at each iteration and which has been applied to the synthesis of conjugated rigid rods as well as amorphous and crystalline oligomers and polymers. The synthesis of perfectly defined oligomers in respect to emerging highly efficient and orthogonal chemistries will also be highlighted.

引用

页码：147 / 168

页数：22

共 155 条

[41] Experimental requirements for an efficient control of free-radical polymerizations via the reversible addition-fragmentation chain transfer (RAFT) process [J].

Favier, Arnaud ;

Charreyre, Marie-Therese .

MACROMOLECULAR RAPID COMMUNICATIONS, 2006, 27 (09) :653-692

[42] Sensors using octaaniline for volatile organic compounds [J].

Feng, J ;

MacDiarmid, AG .

SYNTHETIC METALS, 1999, 102 (1-3) :1304-1305

[43] Stability of polythiophene-based transistors and circuits [J].

Ficker, J ;

Ullmann, A ;

Fix, W ;

Rost, H ;

Clemens, W .

JOURNAL OF APPLIED PHYSICS, 2003, 94 (04) :2638-2641

[44] Fast polymer integrated circuits [J].

Fix, W ;

Ullmann, A ;

Ficker, J ;

Clemens, W .

APPLIED PHYSICS LETTERS, 2002, 81 (09) :1735-1737

[45] Synthesis of uniform, non-natural oligomers [J].

Franz, Nadja ;

Kreutzer, Georg ;

Klok, Harm-Anton .

SYNLETT, 2006, (12) :1793-1815

[46] A Post-Modification Strategy for the Synthesis of Uniform, Hydrophilic/Hydrophobic Patterned α-Hydroxy Acid Oligomers [J].

Franz, Nadja ;

Menin, Laure ;

Klok, Harm-Anton .

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2009, 2009 (31) :5390-5405

[47] High-Efficiency Preparation of Macrocyclic Diblock Copolymers via Selective Click Reaction in Micellar Media [J].

Ge, Zhishen ;

Zhou, Yueming ;

Xu, Jian ;

Liu, Hewen ;

Chen, Daoyong ;

Liu, Shiyong .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (05) :1628-+

[48] Optical bandgaps of π-conjugated organic materials at the polymer limit:: Experiment and theory [J].

Gierschner, Johannes ;

Cornil, Jerome ;

Egelhaaf, Hans-Joachim .

ADVANCED MATERIALS, 2007, 19 (02) :173-191

[49] Access to cyclic polystyrenes via a combination of reversible addition fragmentation chain transfer (RAFT) polymerization and click chemistry [J].

Goldmann, Anja S. ;

Quemener, Damien ;

Millard, Pierre-Eric ;

Davis, Thomas P. ;

Stenzel, Martina H. ;

Barner-Kowollik, Christopher ;

Wuller, Axel H. E. .

POLYMER, 2008, 49 (09) :2274-2281

[50]

Grave C, 2002, EUR J ORG CHEM, V2002, P3075

← 1 2 3 4 5 6 7 8 9 10 →