Investigations of La Rioja Terroir for Wine Production Using 1H NMR Metabolomics

被引:99
作者
Lopez-Rituerto, Eva [1 ]
Savorani, Francesco [2 ]
Avenoza, Alberto [1 ]
Busto, Jesus H. [1 ]
Peregrina, Jesus M. [1 ]
Engelsen, Soren Balling [2 ]
机构
[1] Univ La Rioja, UA CSIC, Ctr Invest Sintesis Quim, Dept Quim, E-26006 Logrono, Spain
[2] Univ Copenhagen, Fac Sci, Dept Food Sci, DK-1958 Frederiksberg C, Denmark
关键词
Wine; NMR; chemometrics; metabolomics; Rioja; isopentanol; isobutanol; carbohydrates; MAGNETIC-RESONANCE-SPECTROSCOPY; CANONICAL VARIATES ANALYSIS; RED WINES; MALOLACTIC FERMENTATION; QUANTITATIVE H-1-NMR; GEOGRAPHICAL ORIGIN; GROWING AREAS; GRAPE BERRIES; FOOD-SCIENCE; CHEMOMETRICS;
D O I
10.1021/jf204361d
中图分类号
S [农业科学];
学科分类号
09 ;
摘要
In this study, La Rioja wine terroir was investigated by the use of H-1 NMR metabolomics on must and wine samples. Rioja is a small wine region in central northern Spain which can geographically be divided into three subareas (Rioja Alta, Rioja Baja, and Rioja Alavesa). The winemaking process from must, through alcoholic and malolactic fermentation, was followed by NMR metabolomics and chemometrics of nine wineries in the Rioja subareas (terroirs). Application of interval extended canonical variate analysis (iECVA) showed discriminative power between wineries which are geographically very close. Isopentanol and isobutanol compounds were found to be key biomarkers for this differentiation.
引用
收藏
页码:3452 / 3461
页数:10
相关论文
共 38 条
[21]   Chemometrics in food science - a demonstration of the feasibility of a highly exploratory, inductive evaluation strategy of fundamental scientific significance [J].
Munck, L ;
Norgaard, L ;
Engelsen, SB ;
Bro, R ;
Andersson, CA .
CHEMOMETRICS AND INTELLIGENT LABORATORY SYSTEMS, 1998, 44 (1-2) :31-60
[22]   High-resolution NMR and diffusion-ordered spectroscopy of port wine [J].
Nilsson, M ;
Duarte, IF ;
Almeida, C ;
Delgadillo, I ;
Goodfellow, BJ ;
Gil, AM ;
Morris, GA .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2004, 52 (12) :3736-3743
[23]   Interval partial least-squares regression (iPLS):: A comparative chemometric study with an example from near-infrared spectroscopy [J].
Norgaard, L ;
Saudland, A ;
Wagner, J ;
Nielsen, JP ;
Munck, L ;
Engelsen, SB .
APPLIED SPECTROSCOPY, 2000, 54 (03) :413-419
[24]   Fluorescence spectroscopy and chemometrics for classification of breast cancer samples -: a feasibility study using extended canonical variates analysis [J].
Norgaard, Lars ;
Soletormos, Gyorgy ;
Harrit, Niels ;
Albrechtsen, Morten ;
Olsen, Ole ;
Nielsen, Dorte ;
Kampmann, Kristoffer ;
Bro, Rasmus .
JOURNAL OF CHEMOMETRICS, 2007, 21 (10-11) :451-458
[25]   A modification of canonical variates analysis to handle highly collinear multivariate data [J].
Norgaard, Lars ;
Bro, Rasmus ;
Westad, Frank ;
Engelsen, Soren Balling .
JOURNAL OF CHEMOMETRICS, 2006, 20 (8-10) :425-435
[26]   Microclimate influence on mineral and metabolic profiles of grape berries [J].
Pereira, G. E. ;
Gaudillere, J. -P. ;
Pieri, P. ;
Hilbert, G. ;
Maucourt, M. ;
Deborde, C. ;
Moing, A. ;
Rolin, D. .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2006, 54 (18) :6765-6775
[27]   1H NMR metabolite fingerprints of grape berry:: Comparison of vintage and soil effects in Bordeaux grapevine growing areas [J].
Pereira, GE ;
Gaudillere, JP ;
van Leeuwen, C ;
Hilbert, G ;
Maucourt, M ;
Deborde, C ;
Moing, A ;
Rolin, D .
ANALYTICA CHIMICA ACTA, 2006, 563 (1-2) :346-352
[28]   1H NMR and chemometrics to characterize mature grape berries in four wine-growing areas in Bordeaux, France [J].
Pereira, GE ;
Gaudillere, JP ;
Van Leeuwen, C ;
Hilbert, G ;
Lavialle, O ;
Maucourt, M ;
Deborde, C ;
Moing, A ;
Rolin, D .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2005, 53 (16) :6382-6389
[29]   Recent technological advances for the determination of food authenticity [J].
Reid, Linda M. ;
O'Donnell, Colm P. ;
Downey, Gerard .
TRENDS IN FOOD SCIENCE & TECHNOLOGY, 2006, 17 (07) :344-353
[30]   Application of capillary electrophoresis to determine metal cations, anions, organic acids, and carbohydrates in some Pinot Noir red wines [J].
Rovio, Stella ;
Siren, Kimmo ;
Siren, Heli .
FOOD CHEMISTRY, 2011, 124 (03) :1194-1200