Helicity inversion in responsive foldamers induced by achiral halide ion guests

被引：291

作者：

Meudtner, Robert M. ^{[1
]}

Hecht, Stefan ^{[1
]}

机构：

[1] Humboldt Univ, Dept Chem, D-12489 Berlin, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 26期

关键词：

chirality; click chemistry; foldamers; helical polymers; helix inversion;

D O I：

10.1002/anie.200800796

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Graph Presented) A surprising about-face: Click chemistry was used for the efficient synthesis of a newclass of foldamers, referred to as clickamers, that display unusual folding and recognition properties. In the presence of halide ions - achiral species - they undergo an unprecedented helix inversion. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：4926 / 4930

页数：5

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