The modular synthesis of functional porous coordination networks

被引:110
作者
Kawano, Masaki [1 ]
Kawamichi, Takehide [1 ]
Haneda, Tsuyoshi [1 ]
Kojima, Takahiro [2 ]
Fujita, Makoto [1 ,3 ]
机构
[1] Univ Tokyo, Sch Engn, Dept Appl Chem, Tokyo 1138656, Japan
[2] Genesis Res Inst Inc, Bunkyo Ku, Tokyo 1138656, Japan
[3] JST, CREST, Tokyo 1138656, Japan
关键词
METAL-ORGANIC FRAMEWORK; CONSTRUCTION; CHANNELS; SORPTION; DESIGN; ROBUST;
D O I
10.1021/ja0752540
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Facile control of pore nature by simply replacing a cartridge is a new approach to the library synthesis of a family of porous networks. We succeeded in the preparation of various biporous networks via modular synthesis and the fine-tuning of the channel atmosphere by simple modification of the cartridge molecules. Noteworthy is that alcohol molecules are selectively recognized by the biporous network.
引用
收藏
页码:15418 / +
页数:3
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