Incorporation of three phenylacetylene molecules into an RhMo2S4 trinuclear sulfido cluster core, forming bridging metallathiacyclobutene and dithiolene moieties

被引：25

作者：

Ikada, T

Mizobe, Y

Hidai, M

机构：

[1] Univ Tokyo, Inst Ind Sci, Meguro Ku, Tokyo 1538505, Japan

[2] Tokyo Univ Sci, Fac Ind Sci & Technol, Dept Mat Sci & Technol, Noda, Chiba 2788510, Japan

来源：

ORGANOMETALLICS | 2001年 / 20卷 / 21期

关键词：

D O I：

10.1021/om010417t

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The trinuclear sulfido cluster [{Rh(PPh3)(2)}-(mu (3)-S)(mu (2)-S)(3){Mo(S2CNEt2)}(2)(mu (2)-Cl)] (2a) reacted readily with three PhC equivalent to CH molecules to afford [{Rh(SCPh=CH)Cl(PPh3)}{Mo(SCPh=CH)(S2CNEt2)}{Mo(S2C2HPh)(S2CNEt2)}], the structure of which, as well as that of the PMePh2 analogue of 2a, have been determined by X-ray analyses.

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页码：4441 / 4444

页数：4

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