Hydrogenation and hydrogenolysis of thiophenic molecules catalysed by soluble metal complexes

被引：142

作者：

Bianchini, C

Meli, A

机构：

[1] Istituto per lo Studio della Stereochimica ed Energetica dei Composti di Coordinazione, ISSECC-CNR, 50132 Firenze

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1996年 / 06期

关键词：

D O I：

10.1039/dt9960000801

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In this review are discussed the known hydrogenation and hydrogenolysis reactions of thiophenic molecules catalysed by soluble metal complexes. Homogeneous desulfurization reactions are also briefly summarized. The mechanistic information provided by the homogeneous modelling studies is critically evaluated through comparisons with the surface reactions that have been proposed to be implicated in the heterogeneous hydrodesulfurization catalysis.

引用

页码：801 / 814

页数：14

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