THIOPHENE C-S BOND-CLEAVAGE BY RHODIUM AND IRIDIUM - AN UNPRECEDENTED BRIDGING MODE OF THE OPEN C4H4S FRAGMENT

被引：17

作者：

BACCHI, A

BIANCHINI, C

HERRERA, V

JIMENEZ, MV

MEALLI, C

MELI, A

MONETI, S

PERUZZINI, M

SANCHEZDELGADO, RA

VIZZA, F

机构：

[1] CNR,IST STUDIO STEREOCHIM & ENERGET COMPOSTI COOR,I-50132 FLORENCE,ITALY

[2] INST VENEZOLANO INVEST CIENT,CARACAS 1020A,VENEZUELA

[3] UNIV PARMA,DIPARTIMENTO CHIM GEN & INORGAN,I-43100 PARMA,ITALY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 09期

关键词：

D O I：

10.1039/c39950000921

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The complexes [{(triphos)M}(2)(mu-eta(3),eta(4)-SC4H4)](Y)(2) (M = Ir, Y = BPh(4); M = Rh, Y = PF6) are obtained by reaction of thiophene with either [(triphos)Ir(eta(4)-C6H6)]BPh(4) in Me(2)SO at 80 degrees C or [(triphos)RhCl(C2H4)] + TlPF6 in THF at room temperature; a single-crystal X-ray diffraction analysis of the iridium complex shows that an open C4H4S moiety sits astride two metal centres; the bridge-bonding mode implies the sharing of four electron pairs with the metals.

引用

页码：921 / 922

页数：2

共 16 条

[1] SIR92 - a program for automatic solution of crystal structures by direct methods
ALTOMARE, A
CASCARANO, G
GIACOVAZZO, G
GUAGLIARDI, A
BURLA, MC
POLIDORI, G
CAMALLI, M
[J]. JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1994, 27 : 435 - 435
[2] STRUCTURAL ASPECTS OF THIOPHENE COORDINATION IN TRANSITION-METAL COMPLEXES
ANGELICI, RJ
[J]. COORDINATION CHEMISTRY REVIEWS, 1990, 105 : 61 - 76
[3] HETEROGENEOUS CATALYSIS OF THE HYDRODESULFURIZATION OF THIOPHENES IN PETROLEUM - AN ORGANOMETALLIC PERSPECTIVE OF THE MECHANISM
ANGELICI, RJ
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1988, 21 (11) : 387 - 394
[4] ANGELICI RJ, 1994, ENCY INORGANIC CHEM, V3, P1433
[5] OPENING, DESULFURIZATION, AND HYDROGENATION OF THIOPHENE AT IRIDIUM - AN EXPERIMENTAL-STUDY IN A HOMOGENEOUS PHASE
BIANCHINI, C
MELI, A
PERUZZINI, M
VIZZA, F
FREDIANI, P
HERRERA, V
SANCHEZDELGADO, RA
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (07) : 2731 - 2742
[6] TRIPODAL POLYPHOSPHINE LIGANDS IN HOMOGENEOUS CATALYSIS .1. HYDROGENATION AND HYDROFORMYLATION OF ALKYNES AND ALKENES ASSISTED BY ORGANORHODIUM COMPLEXES WITH MEC(CH2PPH2)3
BIANCHINI, C
MELI, A
PERUZZINI, M
VIZZA, F
FREDIANI, P
RAMIREZ, JA
[J]. ORGANOMETALLICS, 1990, 9 (01) : 226 - 240
[7] BIANCHINI C, 1986, STEREOCHEMISTRY ORGA, P147
[8] THIOPHENE CARBON SULFUR BOND-CLEAVAGE BY COBALT - SYNTHESIS, STRUCTURE, AND DYNAMICS OF [(C5ME5)CO]2(C4H4S)
JONES, WD
CHIN, RM
[J]. ORGANOMETALLICS, 1992, 11 (07) : 2698 - 2700
[9] MECHANISM OF FORMATION OF C-C BONDS IN THE RING-OPENING AND COUPLING OF THIOPHENE BY (C5ME5)RH(C2H4)2
JONES, WD
CHIN, RM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (25) : 9851 - 9858
[10] CARBON-SULFUR BOND-CLEAVAGE BY COBALT - REACTION OF CP-ASTERISK-CO(C2H4)2 WITH DIBENZOTHIOPHENE
JONES, WD
CHIN, RM
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1994, 472 (1-2) : 311 - 316

← 1 2 →