DESULFURIZATION OF THIOPHENES WITH RUTHENIUM CLUSTERS

被引：42

作者：

ARCE, AJ ^{[1
]}

ARROJO, P ^{[1
]}

DEEMING, AJ ^{[1
]}

DESANCTIS, Y ^{[1
]}

机构：

[1] UNIV LONDON UNIV COLL,DEPT CHEM,LONDON WC1H 0AJ,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1992年 / 15期

关键词：

D O I：

10.1039/dt9920002423

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The cluster [Ru3(CO)12] reacts with 2-methylthiophene in refluxing tetrahydrofuran to give products of oxidative addition by C-H cleavage, [Ru3(mu-H)(mu-C4H2MeS)(CO)10] (exo and endo), as well as two compounds derived by S-C bond cleavage, [Ru2(mu-C4H3Me)(CO)6] and [Ru4(mu-3-S)(mu-C4H3Me)(CO)11] (X-ray structure determined), this being the first example of the fragmentation of a thiophene to leave both the inorganic and the organic fragments, S and C4H3Me, co-ordinated in the same organometallic compound.

引用

页码：2423 / 2424

页数：2

共 12 条

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