Single electron transfer approaches to the practical synthesis of aromatic and heterocyclic-CF2H derivatives

被引：42

作者：

Dolbier, WR

Médebielle, M

Ait-Mohand, S

机构：

[1] Univ Florida, Dept Chem, Gainesville, FL 32611 USA

[2] Univ Paris 07, UMR CNRS 7591, Electrochim Mol Lab, F-75251 Paris 05, France

来源：

TETRAHEDRON LETTERS | 2001年 / 42卷 / 29期

关键词：

D O I：

10.1016/S0040-4039(01)00873-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Single electron transfer (SET) approaches with organic reductants such as sodium hydroxymethanesulfinate (Rongalite((R))), sodium dithionite (regarded as precursors of sulfoxylate radical anion) and tetrakis(dimethylamino)ethylene (TDAE) were employed for the reductive dehalogenation of a series of halogeno-difluoromethylated aromatics and heterocycles, and for the practical synthesis of the corresponding difluoromethylated derivatives. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：4811 / 4814

页数：4

共 23 条

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