Highly Soluble Poly(thienylenevinylene) Derivatives with Charge-Carrier Mobility Exceeding 1 cm2V-1s-1

被引:64
作者
Kim, Juhwan [1 ]
Lim, Bogyu [2 ]
Baeg, Kang-Jun [3 ]
Noh, Yong-Young [4 ]
Khim, Dongyoon [1 ]
Jeong, Hyung-Gu [1 ]
Yun, Jin-Mun [1 ]
Kim, Dong-Yu [1 ,5 ]
机构
[1] Gwangju Inst Sci & Technol, Sch Mat Sci & Engn, Heeger Ctr Adv Mat, Kwangju 500712, South Korea
[2] Stanford Univ, Dept Mat Sci & Engn, Ctr Adv Mol Photovolta CAMP, Stanford, CA 94305 USA
[3] Elect & Telecommun Res Inst ETRI, Convergence Components & Mat Res Lab, Taejon 305700, South Korea
[4] Hanbat Natl Univ, Dept Chem Engn, Taejon 305719, South Korea
[5] Gwangju Inst Sci & Technol, Dept Nanobio Mat & Elect, Res Inst Solar & Sustainable Energies, Kwangju 500712, South Korea
基金
新加坡国家研究基金会;
关键词
conjugated polymer; polymer semiconductor; organic electronics; OTFTs; thienylenevinylene; THIN-FILM TRANSISTORS; THIENYLENEVINYLENE OLIGOMERS; ORGANIC PHOTOVOLTAICS; SIDE-CHAINS; SOLAR-CELLS; COPOLYMERS; VINYLENE; TRANSPORT; POLYMERS; THIOPHENE;
D O I
10.1021/cm2021802
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We report synthesis and characterization of high performance p-type conjugated polymers containing alkyl-substituted thienylenevinylene (PC6TV12T and PC12TV12T) as an active layer for organic thin film transistors (OTFTs). Maximum mobility of annealed PC6TV12T and PC12TV12T films measured in OTFTs showed 0.47 and 1.05 cm2V-1s-1, respectively, in the top-gate/bottom-contact (TG/BC) configuration. © 2011 American Chemical Society.
引用
收藏
页码:4663 / 4665
页数:3
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