Thieno[3,2-b]thiophene-Diketopyrrolopyrrole-Containing Polymers for High-Performance Organic Field-Effect Transistors and Organic Photovoltaic Devices

被引:834
作者
Bronstein, Hugo [1 ]
Chen, Zhuoying [2 ]
Ashraf, Rap Shahid [1 ]
Zhang, Weimin [1 ]
Du, Junping [1 ]
Durrant, James R. [1 ]
Tuladhar, Pabitra Shakya [1 ]
Song, Kigook [3 ]
Watkins, Scott E.
Geerts, Yves [5 ]
Wienk, Martijn M. [4 ]
Janssen, Rene A. J. [4 ]
Anthopoulos, Thomas [1 ]
Sirringhaus, Henning [2 ]
Heeney, Martin [1 ]
McCulloch, Iain [1 ]
机构
[1] Univ London Imperial Coll Sci Technol & Med, London SW7 2AZ, England
[2] Univ Cambridge, Cavendish Lab, Cambridge CB3 0HE, England
[3] Kyung Hee Univ, Yongin 446701, Gyeonggi Do, South Korea
[4] Eindhoven Univ Technol, NL-5600 MB Eindhoven, Netherlands
[5] Univ Libre Bruxelles, B-1050 Brussels, Belgium
关键词
THIN-FILM TRANSISTORS; EFFICIENT SOLAR-CELLS; SEMICONDUCTING POLYMERS; MOBILITY; DIKETOPYRROLOPYRROLE; DEPENDENCE; COPOLYMER;
D O I
10.1021/ja110619k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We report the synthesis and polymerization of a novel thieno[3,2-b]thiophene-diketopyrrolopyrrole-based monomer. Copolymerization with thiophene afforded a polymer with a maximum hole mobility of 1.95 cm(2) V(-1) s(-1) which is the highest mobility from a polymer-based OFET reported to date. Bulk-heterojunction solar cells comprising this polymer and PC(71)BM gave a power conversion efficiency of 5.4%.
引用
收藏
页码:3272 / 3275
页数:4
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